Rebecca Romijn proved she can kick major butt in the X-Men films and now, she’s bringing her lethal moves to Chuck‘s final season.

EW has learned exclusively that the actress will appear in the sixth episode of the upcoming season (which starts Oct. 21) as Robin Cunnings, an elite Special Agent with the CIA who’s as cold and calculating as she is sexy, and is known for her barbaric (yet highly effective) interrogation techniques.

As expected, her appearance brings nothing but bad news for Chuck and Co. Her character is said to be a member of a rogue group within the CIA that is planning to frame Chuck for the crime of the century.

Romijn, who is currently appearing on the Adult Swim comedy series NTSF:SD:SUV, last graced network TV on ABC’s Eastwick and Ugly Betty.

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This weekend, Rebecca Romijn was a presenter at the 2011 Primetime Creative Arts Emmy Awards in Los Angeles. I have just added 248 HQ and MQ photos from the red carpet, audience, backstage and show into our photo gallery!

Justified‘s Walton Goggins and Graham Yost, Glee‘s Chris Colfer and Brad Falchuk, and The Pee-Wee Herman Show on Broadway‘s Paul Reubens are among the additional presenters announced today for the 2011 Primetime Creative Arts Emmy Awards, set for Sept. 10 at the Nokia Theatre L.A. LIVE in Los Angeles. Rebecca Romijn and Paul Scheer (NTSF:SD:SUV), Priscilla Presley and Steve Binder (Elvis’ ’68 Comeback Special), and H. Jon Benjamin and Adam Reed (Archer) also will appear to hand out awards.

They join presenters revealed last week. The ceremony will air Sept. 17 on ReelzChannel.

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Its been announced that Rebecca Romijn is starring in a TV movie called “Possessing Piper Rose” that will be airing on the Lifetime TV network on October 24th at 9:00pm ET/PT!

POSSESSING PIPER ROSE premieres Monday, October 24, 9:00pm ET/PT

The story of a couple (Rebecca Romijn, X-Men, Ugly Betty and David Cubitt, Medium, Lifetime’s Bond of Silence) so desperate to adopt a child they might even bend the rules to get one. But when the three-year old little girl of their dreams arrives, strange, inexplicable events begin to happen that threaten the couple’s lives.

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I have added 169 screen captures from episodes 1, 3 and 5 of “NTSF:SD:SUV” into our photo gallery! “NTSF:SD:SUV” is the new series that Rebecca Romijn is starring in that airs on Adult Swim on Thursday nights. Also added are screen captures from the trailer and opening credits for the series.

Rebecca Romijn and her husband Jerry were spotted grabbing lunch in Los Angeles on August 15th. I have just added 10 HQ photos of them into our photo gallery!

“I feel like a magician pulling tricks out of my hat!” Rebecca Romijn tells Us Weekly about the must-haves in her $1,000 Coach ‘Kristin’ satchel. “I’m like a walking entertainment center.”

But in addition to being a mom to twin two-year-old girls Charlie and Dolly and having the essentials to keep them occupied, the actress also relies on a few organizational and grooming items to help her get through the day-to-day. “The iPhone is great for toddlers,” the 38-year-old explains. “I have Itsy Bitsy Spider and Old MacDonald apps.” The complete list, below:

Smashbox O-Gloss Intuitive Lip Gloss ($22, sephora.com)

Kevyn Aucoin The Celestial Bronzing Veil ($45, dermstore.com)

Oliver Peoples Shean Sunglasses ($310, oliverpeoples.com)

VIX Bikini ($160, vixswimwear.com)

Lodis Audrey Mini Card Case ($32, lodis.com)

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I have added 482 screen captures of Rebecca Romijn into our gallery. There is captures from her appearance on “Sesame Street”, captures from 3 videos that were made for the website “Funny or Die” and captures from behind the scenes of Rebecca’s “Got Milk?” and “Vegas” photo shoots.

Paul Scheer and friends’ fake trailer for National Terrorism Strike Force: San Diego: Sport Utility Vehicle gets a real live show on Adult Swim. A partial list of the people you will recognize: Martin Starr, Adam Scott in a wheelchair, Rebecca Romijn, Jeff Goldblum, Rob Riggle, Wilmer Valderrama (we think), Kate Mulgrew, Ed Helms, and many more.

I have just added 11 photos of Rebecca Romijn arriving to LAX airport in Los Angeles on May 20th into our photo gallery!